Dongba pictographic is the only pictographic script still in use in the world. Its pictorial ideographic features carry rich cultural and contextual information. However, due to the lack of relevant datasets, research on semantic understanding of Dongba hieroglyphs has progressed slowly. To this end, we constructed DongbaMIE - the first dataset focusing on multimodal information extraction of Dongba pictographs. The dataset consists of images of Dongba hieroglyphic characters and their corresponding semantic annotations in Chinese. It contains 23,530 sentence-level and 2,539 paragraph-level high-quality text-image pairs. The annotations cover four semantic dimensions: object, action, relation and attribute. Systematic evaluation of mainstream multimodal large language models shows that the models are difficult to perform information extraction of Dongba hieroglyphs efficiently under zero-shot and few-shot learning. Although supervised fine-tuning can improve the performance, accurate extraction of complex semantics is still a great challenge at present.