A text corpus centered on events is foundational to research concerning the detection, representation, reasoning, and harnessing of online events. The majority of current event-based datasets mainly target sentence-level tasks, thus to advance event-related research spanning from sentence to document level, this paper introduces DEIE, a unified large-scale document-level event information extraction dataset with over 56,000+ events and 242,000+ arguments. Three key features stand out: large-scale manual annotation (20,000 documents), comprehensive unified annotation (encompassing event trigger/argument, summary, and relation at once), and emergency events annotation (covering 19 emergency types). Notably, our experiments reveal that current event-related models struggle with DEIE, signaling a pressing need for more advanced event-related research in the future.