Text-Centric Visual Question Answering (TEC-VQA) in its proper format not only facilitates human-machine interaction in text-centric visual environments but also serves as a de facto gold proxy to evaluate AI models in the domain of text-centric scene understanding. Nonetheless, most existing TEC-VQA benchmarks focus on high-resource languages like English and Chinese. Despite pioneering works expanding multilingual QA pairs in non-text-centric VQA datasets through translation engines, the translation-based protocol encounters a substantial “visual-textual misalignment” problem when applied to TEC-VQA. Specifically, it prioritizes the text in question-answer pairs while disregarding the visual text present in images. Moreover, it fails to address complexities related to nuanced meaning, contextual distortion, language bias, and question-type diversity. In this work, we tackle multilingual TEC-VQA by introducing MTVQA, the first benchmark featuring high-quality human expert annotations across 9 diverse languages, consisting of 6,778 question-answer pairs across 2,116 images. Further, by comprehensively evaluating numerous state-of-the-art Multimodal Large Language Models (MLLMs), including Qwen2.5-VL, InternVL-2.5, GPT-4o, GPT-4V, Claude3, and Gemini, on the MTVQA benchmark, it is evident that there is still a large room for performance improvement (InternVL-2.5 scoring 32.2 versus 79.7 for human performance), underscoring the value of MTVQA. By providing a dataset with nuanced multilingual annotations, MTVQA aims to set a new standard for benchmarks, fostering advancements in multilingual visual text comprehension.