Recent large-scale vision-language pre-training depends on image-text global alignment by contrastive learning and is further boosted by fine-grained alignment in a weakly contrastive manner for cross-modal retrieval. Nonetheless, besides semantic matching learned by contrastive learning, cross-modal retrieval also largely relies on object matching between modalities. This necessitates fine-grained categorical discriminative learning, which however suffers from scarce data in full-supervised scenarios and information asymmetry in weakly-supervised scenarios when applied to cross-modal retrieval. To address these issues, we propose expansive lexicon-patch alignment (ELA) to align image patches with a vocabulary rather than only the words explicitly in the text for annotation-free alignment and information augmentation, thus enabling more effective fine-grained categorical discriminative learning for cross-modal retrieval. Experimental results show that ELA could effectively learn representative fine-grained information and outperform state-of-the-art methods on cross-modal retrieval.