As Multimodal Large Language Models (MLLMs) develop, their potential security issues have become increasingly prominent. **Machine Unlearning (MU)**, as an effective strategy for forgetting specific knowledge in training data, has been widely used in privacy protection. However, *MU for safety in MLLM has yet to be fully explored*. To address this issue, we propose , a safety unlearning benchmark for MLLMs, consisting of 3,000 images and 28.8K VQA pairs. We comprehensively evaluate unlearning methods from two perspectives: **_forget quality_** and **_model utility_**. Our findings show that existing MU methods struggle to maintain model performance while implementing the forget operation and often suffer from **_over-forgetting_**. Hence, we introduce **Prompt Decouple (PD) Loss** to alleviate over-forgetting through decouple prompt during unlearning process. To quantitatively measure over-forgetting mitigated by PD Loss, we propose a new metric called **Safe Answer Refusal Rate (SARR)**. Experimental results demonstrate that combining PD Loss with existing unlearning methods can effectively prevent over-forgetting and achieve a decrease of 79.5% in the SARR metric of LLaVA-7B and LLaVA-13B, while maintaining forget quality and model utility. Our code and dataset will be released upon acceptance. **Warning: This paper contains examples of harmful language and images, and reader discretion is recommended.**