Remarkable progress on large language models (LLMs), particularly in English, has facilitated impressive capabilities in following human instructions. However, there remains a noticeable gap in instruction fine-tuning for Chinese, where the complex linguistic features pose significant challenges. Existing datasets, generally distilled from English-centric LLMs, are not well-aligned with Chinese users’ interaction patterns. To bridge this gap, we introduce COIG-CQIA, a new Chinese instruction tuning dataset derived from various real-world data resources and undergoing comprehensive human verification. We conduct extensive experiments on COIG-CQIA, and compare them with strong baseline models and datasets. The experimental results show that models trained on COIG-CQIA achieve highly competitive performance in diverse benchmarks. Additionally, our findings offer several insights for designing effective Chinese instruction-tuning datasets and data mixing strategies. Our dataset are available at https://huggingface.co/datasets/m-a-p/COIG-CQIA.