Philology, the study of ancient manuscripts, demands years of professional training in ex-tensive knowledge memorization and manual textual retrieval. Despite these requirements align closely with strengths of recent successful Large Language Models (LLMs), the scarcity of high-quality, specialized training data has hindered direct applications. To bridge this gap, we curated the PhiloCorpus-ZH, a rich collec-tion of ancient Chinese texts spanning a millen-nium with 30 diverse topics, including firsthand folk copies. This corpus facilitated the develop-ment of PhiloGPT, the first LLM tailored for discovering ancient Chinese manuscripts. To effectively tackle complex philological tasks like restoration, attribution, and linguistic anal-ysis, we introduced the PhiloCoP framework. Modeled on the analytical patterns of philol-ogists, PhiloCoP enhances LLM’s handling of historical linguistic peculiarities such as phonetic loans, polysemy, and syntactic inver-sions. We further integrated these tasks into the PhiloBenchmark, establishing a new standard for evaluating ancient Chinese LLMs address-ing philology tasks. Deploying PhiloGPT in practical scenarios has enabled Dunhuang spe-cialists to resolve philology tasks, such as iden-tifying duplication of copied text and assisting archaeologists with text completion, demon-strating its potential in real-world applications.