The quality of Supervised Fine-Tuning (SFT) data plays a critical role in enhancing the conversational capabilities of Large Language Models (LLMs). However, the availability of high-quality human-annotated SFT data has become a significant bottleneck for LLMs, necessitating a greater reliance on synthetic training data. In this work, we introduce Condor, a two-stage synthetic data generation framework that incorporates World Knowledge Trees and Self-Reflection Refinement to produce high-quality SFT data at scale. Our experimental results demonstrate that a base model fine-tuned on only 20K Condor-generated samples achieves superior performance compared to instruct model trained with RLHF. The additional refinement stage in Condor further enables iterative self-improvement for LLMs at various scales (up to 72B), validating the effectiveness of our approach. Furthermore, our investigation into the scaling of synthetic data in post-training reveals substantial unexplored potential for performance improvements, opening promising avenues for future research.