Probing techniques for large language models (LLMs) have primarily focused on English, overlooking the vast majority of other world’s languages. In this paper, we extend these probing methods to a multilingual context, investigating how LLMs encode linguistic structures across diverse languages. We conduct experiments on several open-source LLM models, analyzing probing accuracy, trends across layers, and similarities between probing vectors for multiple languages. Our key findings reveal: (1) a consistent performance gap between high-resource and low-resource languages, with high-resource languages achieving significantly higher probing accuracy; (2) divergent layer-wise accuracy trends, where high-resource languages show substantial improvement in deeper layers similar to English; and (3) higher representational similarities among high-resource languages, with low-resource languages demonstrating lower similarities both among themselves and with high-resource languages. These results provide insights into how linguistic structures are represented differently across languages in LLMs and emphasize the need for improved structure modeling for low-resource languages.