Grounded Multimodal Named Entity Recognition (GMNER), which aims to extract textual entities, their types, and corresponding visual regions from image-text data, has become a critical task in multimodal information extraction. However, existing methods face two major challenges. First, they fail to address the semantic ambiguity caused by polysemy and the long-tail distribution of datasets. Second, unlike visual grounding which provides descriptive phrases, entity grounding only offers brief entity names which carry less semantic information. Current methods lack sufficient semantic interaction between text and image, hindering accurate entity-visual region matching. To tackle these issues, we propose MAKAR, a Multi-Agent framework based Knowledge-Augmented Reasoning, comprising three agents: Knowledge Enhancement, Entity Correction, and Entity Reasoning Grounding. Specifically, in the named entity recognition phase, the Knowledge Enhancement Agent leverages a Multimodal Large Language Model (MLLM) as an implicit knowledge base to enhance ambiguous image-text content with its internal knowledge. For samples with low-confidence entity boundaries and types, the Entity Correction Agent uses web search tools to retrieve and summarize relevant web content, thereby correcting entities using both internal and external knowledge. In the entity grounding phase, the Entity Reasoning Grounding Agent utilizes multi-step Chain-of-Thought reasoning to perform grounding for each entity. Extensive experiments show that MAKAR achieves state-of-the-art performance on two benchmark datasets. Code is available at: https://github.com/Nikol-coder/MAKAR.