Large Reasoning Models (LRMs) excel at complex problem-solving but frequently overlook specific instruction constraints. Existing alignment methods struggle to balance general reasoning with instruction-following (IF), hindered by dependency on teacher models, reward hacking, and reasoning-answer inconsistencies. We propose PARIF, a two-stage curriculum learning framework based on Reinforcement Learning from Verifiable Rewards (RLVR) to enhance both IF and general reasoning capabilities. The framework employs a correctness proxy across different stages to mitigate reward hacking. Stage I employs a dynamic weighting strategy simultaneously to optimize the model’s reasoning paradigm regarding constraints. Stage II introduces Decoupled-GRPO, which builds upon the first stage to enhance the logical consistency between the reasoning process and the final answer, enabling the model to better leverage its optimized reasoning paradigm. To support the framework, we curate 26,000 high-quality instructions featuring diverse constraints. Extensive experiments demonstrate PARIF’s effectiveness: our 7B model achieves a remarkable 21.25% relative average improvement to the original model across six representative IF tasks, while our 8B model outperforms leading models like DeepSeek-V3 on these IF tasks, effectively pushing the Pareto frontier of instruction following and reasoning for models of comparable scale. We open-source our code and models to facilitate future research.