Although negation is known to challenge large language models (LLMs), benchmarks for evaluating negation understanding—especially in Korean—are scarce. We conduct a corpus-based analysis of Korean negation and show that LLM performance degrades under negation. We then introduce *Thunder-KoNUBench*, a sentence-level negation understanding benchmark that reflects the empirical distribution of Korean negation phenomena. Evaluating 47 LLMs on Thunder-KoNUBench, we analyze the effects of model size and instruction tuning, and perform error analysis to better understand model behavior. We further show that fine-tuning on Thunder-KoNUBench improves negation understanding and broader contextual comprehension in Korean.