Masked diffusion language models present a promising paradigm for language modeling, yet the systematic theoretical analysis and comprehensive empirical validation of their alignment on general tasks remain relatively underexplored. In this paper, we identify the primary challenge for this problem: the high variance in Evidence Lower Bound (ELBO)-based likelihood estimates required for preference optimization. To address this issue, we propose *Variance-Reduced Preference Optimization* (VRPO), a framework that formally analyzes the bias and variance of the preference optimization loss and gradient based on Direct Preference Optimization, showing both are governed by a score-estimator variance. Building on this foundation, we introduce multiple unbiased variance reduction strategies, including optimal budget allocation and antithetic sampling, to improve alignment performance. We demonstrate the effectiveness of VRPO by applying it to LLaDA, a large diffusion language model. The resulting model, LLaDA 1.5, consistently outperforms its SFT-only predecessor consistently across various general benchmarks, such as mathematics (GSM8K +4.7), coding (HumanEval +3.0, MBPP +1.8), and alignment (IFEval +4.0, Arena-Hard +4.3). Furthermore, LLaDA 1.5 demonstrates a highly competitive mathematical performance compared to other strong language MDMs and ARMs. Our model is available at https://huggingface.co/GSAI-ML/LLaDA-1.5.