Given a listener’s native language, some non-native contrasts may be harder to discriminate than others. The computation required to mimic this variable difficulty is not yet known. The present work approaches this question by training small supervised feedforward neural networks to perform Spanish vowel classification and then evaluating model classification of Catalan vowels, thereby approximating Spanish-listeners’ cross-linguistic perception of Catalan. Vowels were extracted from Spanish and Catalan audio corpora, respectively. Ultimately, Spanish models exhibited expected misperception of Catalan’s /e/-/ɛ/, /o/-/ɔ/, and /ɛ/-/a/ contrasts; Spanish-dominant listeners have difficulty perceiving these contrasts, and Spanish models classified Catalan /ɛ/ as /e/ or /a/, and Catalan /ɔ/ as /o/. This demonstrates that small supervised neural models are capable of making specific, cross-linguistic perceptual predictions given realistic input.