In recent years, few-shot relation classification has evoked many research interests. Yet a more challenging problem, i.e. none-of-the-above (NOTA), is under-explored. Existing works mainly regard NOTA as an extra class and treat it the same as known relations. However, such a solution ignores the overall instance distribution, where NOTA instances are actually outliers and distributed unnaturally compared with known ones. In this paper, we propose a density-aware prototypical network (D-Proto) to treat various instances distinctly. Specifically, we design unique training objectives to separate known instances and isolate NOTA instances, respectively. This produces an ideal instance distribution, where known instances are dense yet NOTAs have a small density. Moreover, we propose a NOTA detection module to further enlarge the density of known samples, and discriminate NOTA and known samples accurately. Experimental results demonstrate that the proposed method outperforms strong baselines with robustness towards various NOTA rates. The code will be made public after the paper is accepted.