A syntactic language model (SLM) incrementally generates a sentence with its syntactic tree in a left-to-right manner.We present Generative Pretrained Structured Transformers (GPST), an unsupervised SLM at scale capable of being pre-trained from scratch on raw texts with high parallelism. GPST circumvents the limitations of previous SLMs such as relying on gold trees and sequential training. It consists of two components, a usual SLM supervised by a uni-directional language modeling loss, and an additional composition model, which induces syntactic parse trees and computes constituent representations, supervised by a bi-directional language modeling loss. We propose a representation surrogate to enable joint parallel training of the two models in a hard-EM fashion.We pre-train GPST on OpenWebText, a corpus with billion tokens, and demonstrate the superiority of GPST over GPT-2 with a comparable size in numerous tasks covering both language understanding and language generation. Meanwhile, GPST also significantly outperforms existing unsupervised SLMs on left-to-right grammar induction, while holding a substantial acceleration on training.